Haha I totally haven;t done one of these, Repetitions abound, but I'll totally add some reasons why
:D
Lurve
Anastasia/Dimitri - Anastasia
Belle/Beast - Beauty and the Beast
Bill/CJ - Calamity Jane
Amy/11th Doctor - Doctor Who
Jack Harkness/the Doctor - Doctor Who
Christian Clarke / Syed Masood - Eastenders - I'll now go crawl in a hole for actually admitting this...
Emma/Knightly- Emma
Tracy Turnblad/Link Larkin - Hairspray
Edna Turnblad/ Wilbur Turnblad - Hairspray
Sylar/Claire - Heroes
James Bond/Vesper Lynd - James Bond: Casino Royal
James Bond/Strawberry Fields - James Bond: Quantum of Solace
Aragorn/ Book!Arwen - LotR (sorry Liv, film Arwen is blah)
Eowyn/Faramir - LotR
Sam/Rosie - LotR
Prof Higgins/ Eliza Dolittle- My Fair Lady
Christine/Raoul- Phantom of the Opera
Davy Jones/ Calypso - PotC
James Norrington/ Elizabeth Swann - PotC
Pocahontas/John Smith - Pocahontas (GTFO John Rolfe D:)
Elizabeth/Darcy -Pride and Prejudice
Holmes/ Watson - Sherlock Holmes (2010 film) - its more than friendship, but not sure its full-blown love, they are like hetrosexual life partners... or unwittingly married to one another
Wall-E/Eve- Wall-E
Zorro/Elana- Zorro
Friendship( there's a ton, so I'll list my favs
)
Martha/10 - Doctor Who
Doctor/Donna - Doctor Who
Legolas/Aragorn - LotR
Will/Jack - PotC
Jeremy/James/Richard - Top Gear (they are totally BFFs)
Owen/Jack- Torchwood (are they friends... I like their weird semi-hate relationship anyway)
Elphaba/Glinda - Wicked
...I also have a ton of slightly embarrassing fandom ships, which I won't list here